Structural Transitions in MIL-53 (Cr): View from Outside and Inside
نویسندگان
چکیده
منابع مشابه
Structural transitions in MIL-53 (Cr): view from outside and inside.
We present a unified thermodynamic description of the breathing transitions between large pore (lp) and narrow pore (np) phases of MIL-53 (Cr) observed during the adsorption of guest molecules and the mechanical compression in the process of mercury porosimetry. By revisiting recent experimental data on mercury intrusion and in situ XRD during CO(2) adsorption, we demonstrate that the magnitude...
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ژورنال
عنوان ژورنال: Langmuir
سال: 2011
ISSN: 0743-7463,1520-5827
DOI: 10.1021/la200094x